Syntagma Square is surrounded by traffic-entrenched streets, but luckily, almost all buses and subway lines stop here, so there's no excuse not to visit this important site.
Starting underground, in the new subway station, you will be marvel at the museum-like exhibits the city has set up. (Apparently, it took years to build this section of subway line due to all the ancient artifacts they kept uncovering as they dug.) There are skeletons, pottery, tombs, and all kinds of fascinating items on display in this amazing station. One of the walls has actually been preserved as the trenches of an archaeological dig. Kids of all ages will be very impressed!
Above ground, across from the square, sits the majestic parliament building, with the tomb of the unknown soldier guarded by evzones wearing the traditional Greek costumes. There's even a changing of the guard ceremony if you arrive on the hour.
Also across Syntagma Square is the gorgeous Grande Bretagna Hotel. It's the most prestigious hotel in Athens and has a rich history of hosting dignitaries.